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31.
Ram C. Maurya Deen D. Mishra Surendra K. Jaiswal Sudipta Mukherjee 《Transition Metal Chemistry》1992,17(5):381-383
Some new low-spin hexacoordinated cyanonitrosyl complexes of Cr1 of the type [Cr(NO)(CN)2(L)2(H2)], where L is an aromatic aldehyde oxime or Mannich base, have been prepared by the interaction or K3[Cr(NO)(CN)5]· H2O with L in aqueous AcOH, and characterized by a range of physico-chemical techniques, I.r. data suggest that all the oxime
derivatives and Mannich bases act as monodentate ligands by coordinating through the aromatic nitrogen.
TMC 2564 相似文献
32.
Sea nodules were extensively studied over a wide range of temperature ranging from 77K to 1175K using Mossbauer effect and
ESR. The Mossbauer studies of the nodules at 77K and room temperature show a quadrupole doublet whereas at higher temperatures
magnetic spectra were obtained starting at around 875K which ultimately gives a hyperfine field of around 390 KOe at 1175
K. The Mossbauer spectra recorded at 30K did not show any significant change in the room temperature spectra. The analysis
of the spectra upto 775K showed two positions of FeR+, vie., octahedral and tetrahedral which were varified by ESR of the diluted samples. 相似文献
33.
Ram K. Ganesh 《国际流体数值方法杂志》1991,13(5):557-578
The total drag force on the surface of a body, which is the sum of the form drag and the skin friction drag in a 2D domain, is numerically evaluated by integrating the energy dissipation rate in the whole domain for an incompressible Stokes fluid. The finite element method is used to calculate both the energy dissipation rate in the whole domain as well as the drag on the boundary of the body. The evaluation of the drag and the energy dissipation rate are post-processing operations which are carried out after the velocity field and the pressure field for the flow over a particular profile have been obtained. The results obtained for the flow over three different but constant area profiles—a circle, an ellipse and a cross-section of a prolate spheroid—with uniform inlet velocity are presented and it is shown that the total drag force times the velocity is equal to the total energy dissipation rate in the entire finite flow domain. Hence, by calculating the energy dissipation rate in the domain with unit velocity specified at the far-field boundary enclosing the domain, the drag force on the boundary of the body can be obtained. 相似文献
34.
Ram Kripal 《Solid State Communications》2005,133(1):23-28
The ESR spectrum of Mn2+ doped potassium hydrogen sulphate at liquid nitrogen temperature (77 K) has been analyzed and site of entered Mn2+ in the lattice has been discussed. The values of the zero field parameters that give good fit to the observed ESR spectra have been obtained. The obtained g, A, B, D, E and a values are 2.0002, 66×10−4 cm−1, 26×10−4 cm−1, 59×10−4 cm−1, 32×10−4 cm−1 and −8×10−4 cm−1, respectively. The percentage of covalency of the metal-ligand bond has also been estimated. From the optical absorption study at room temperature, the distortion has been suggested. The observed bands are assigned as transitions from the 6A1g(S) ground state to various excited quartet levels of Mn2+ ion in a cubic crystalline field. The electron repulsion and crystal field parameters B, C, Dq and α providing good fit to the observed optical spectra have been evaluated and the values obtained for the parameters are B=627 cm−1, C=2580 cm−1 , Dq=790 cm−1 and α=76 cm−1. 相似文献
35.
36.
P.Veeraraghavan Ramachandran Kamlesh J Padiya Vivek Rauniyar M.Venkat Ram Reddy Herbert C Brown 《Journal of fluorine chemistry》2004,125(4):615-620
Asymmetric “allyl”boration of pentafluorobenzaldehyde with various α-pinene based “allyl”boranes provides homoallylic alcohols in high de and ee; the alcohols have been converted into δ-lactones via acryloylation, ring-closing metathesis and hydrogenation. Pentafluorophenyl analog of key pharmacophore of statin drugs has been synthesized using diastereoselective epoxidation and regioselective reduction as key steps. 相似文献
37.
The graded Hecke algebra for a finite Weyl group is intimately related to the geometry of the Springer correspondence. A
construction of Drinfeld produces an analogue of a graded Hecke algebra for any finite subgroup of GL(V). This paper classifies all the algebras obtained by applying Drinfeld's construction to complex reflection groups. By giving
explicit (though nontrivial) isomorphisms, we show that the graded Hecke algebras for finite real reflection groups constructed
by Lusztig are all isomorphic to algebras obtained by Drinfeld's construction. The classification shows that there exist
algebras obtained from Drinfeld's construction which are not graded Hecke algebras as defined by Lusztig for real as well
as complex reflection groups.
Received: July 25, 2001 相似文献
38.
R. Ochoa-Land?&#x;n M. Flores-Acosta R. Ram?&#x;rez-Bon H. Arizpe-Chávez F.F. Castillón-Barraza 《Journal of Physics and Chemistry of Solids》2003,64(11):2245-2251
CdS clusters were synthesized in A type zeolite by reaction in alkaline aqueous solution at temperatures from 30 to 70 °C. The optical properties of the samples were studied by diffuse reflectance and photoluminescence spectroscopy. Their crystalline structure and morphology were studied by X-ray diffraction and by transmission and scanning electron microscopy. We found that at lower temperatures the CdS clusters are encapsulated in the zeolite cages. We compared the properties of these clusters with those encapsulated in the cages of zeolites X and Y, prepared by similar methods. CdS clusters smaller than the CdS exciton diameter are also formed outside the cages in the zeolite matrix. The size of these clusters increases with temperature producing a red-shift of the absorption edge in the optical absorption spectra. 相似文献
39.
Bruzón M. S. Gandarias M. L. Muriel C. Ramírez J. Saez S. Romero F. R. 《Theoretical and Mathematical Physics》2003,137(1):1367-1377
We use the classical and nonclassical methods to obtain symmetry reductions and exact solutions of the (2+1)-dimensional integrable Calogero–Bogoyavlenskii–Schiff equation. Although this (2+1)-dimensional equation arises in a nonlocal form, it can be written as a system of differential equations and, in potential form, as a fourth-order partial differential equation. The classical and nonclassical methods yield some exact solutions of the (2+1)-dimensional equation that involve several arbitrary functions and hence exhibit a rich variety of qualitative behavior. 相似文献
40.
Our main object in this paper is to discuss some results on rings with left identity in which certain subsets satisfy some functional identities. 相似文献